石士考 博士 教授

实验研究室：理科群7号楼A区402，404，405

Email: shishikao@hebtu.edu.cn

学习简历

1987年，河北大学本科毕业获化学专业学士学位；

1990年，中国科学院长春物理研究所硕士研究生毕业获固体物理专业硕士学位；

2006年，清华大学博士研究生毕业获材料学专业博士学位。

工作简历

1990年，到广东省珠海科技开发中心工作（工程师）；

1995年，到河北师范大学工作（讲师、副教授）；

2005年至今，河北师范大学365838.com教授；

其中2011-2012年到美国德州大学阿灵顿分校物理系作访问学者（一年）; 2017年到葡萄牙阿威罗大学物理系作访问学者（一年）。

教学相关

讲授课程：物理化学、物理化学实验、化学专业英语；

2012年，作为主编之一编写高等学校教材《物理化学实验》，并由化学工业出版社出版；

多次被化学学院评为最受学生欢迎的教师，被汇华学院评为优秀教师;2014年获河北师范大学教书育人模范教师称号。

研究兴趣

1. 稀土发光材料； 2. 插层组装化学

研究课题与成果

1992年从事的荧光材料开发项目通过广东省珠海市科委鉴定；

1995年获中国科学院科学技术二等奖；

到河北师大后作为项目负责人，多次获国家自然科学基金、河北省自然科学基金、河北省教育厅科研基金及河北师大科研基金资助；

2001年起指导20多名研究生顺利毕业；

2011年入选河北省“三三三人才工程”；

2016年作为项目负责人的研究成果，获河北省自然科学奖三等奖。

发表论文 （2007年后）

1.Shikao Shi*, Keyan Li,Shuping Wang, Ruilong Zong, Guanglei Zhang. Structural characterization andenhanced luminescence of Eu-doped 2CeO₂–0.5La₂O₃composite phosphor powders by a facile solution combustion synthesis, J. Mater. Chem.C, 2017, 5, 4302-4309.

2.Jinglei Li, ShikaoShi*, Ke Ren, Yu Wei, Shuping Wang, Lina Geng, Jianjun Zhang. Structural modification and photoluminescence studies of Euin lamellar fluorphlogopite by the adjustment of layer charge, Mater. Res. Bull., 2017, 94, 1-6.

3.Qingqing Zhao, Ning Ren,* Jianjun Zhang,* LinaGeng, Shuping Wang, Shikao Shi，Three novel Ho(III) complexes with different auxiliary ligands: synthesis,crystal structures and thermal properties, Polyhedron, 2017, 132, 78-89.

4.Chengwei Jin, Qingqing Zhao, Ning Ren,* JianjunZhang,* Lina Geng, Shuping Wang, ShikaoShi，Preparation, crystalstructure and properties of a series of novel lanthanide complexes based on 2,3-dimethoxybenzoic acid and 1,10-phenanthroline, Polyhedron,2017, 135, 206-215.

5.Shikao Shi,* Jinglei Li,Xiaojun Zhang, Shuping Wang, Lina Geng, Jianjun Zhang. Enhanced greenluminescence and energy transfer studies in Ce³⁺/Tb³⁺-codoped α-zirconium phosphate nanosheet, J. Lumin., 2016, 180,214-218.

6.H.Y. Wu,S.K. Shi, C.H. Wang, X.J. Jiang, G. Yu, G.Q. Qin, H. Fu, J. Zhou*.Microwave memristive behavior in split-ringresonator metamaterials, Laser Phys.,2016, 26, 076002.

7.Ye Wang, Panpan Shen, Ning Ren, Jianjun Zhang,* LinaGeng, Shuping Wang, Shikao Shi, Aseries of lanthanide complexes with different N-donor ligands: synthesis,structures, thermal properties and luminescence behaviors. RSC Adv., 2016, 6, 70770–70780.

8.MeiyingSong, Yifang Hou, Longmei Wei, Shuping Wang*, Shutao Yang, Jianjun Zhang, LinaGeng, Shikao Shi. Syntheses, structures, magnetic and thermodynamicsproperties of novel lanthanide complexes with nitronyl nitroxide radical, J.Mole. Stru., 2016, 1107, 174-181.

9.Shikao Shi,* XiaojunZhang, Shuping Wang, Lina Geng, Jianjun Zhang, Wei Chen. Precipitation synthesisand color-tailorable luminescence of α-Zr(HPO₄)₂:RE³⁺(RE=Eu,Tb) nanosheet phosphors, J. Am. Ceram. Soc., 2015, 98,3836-3841.

10.Shikao Shi,* Liying He, Lina Geng,Lanhong Jiang, Shuping Wang, Jianjun Zhang, Ji Zhou. Solution combustionsynthesis and enhanced luminescence of Eu³⁺ -activated Y₂Ce₂O₇phosphor nanopowders, Ceram. Inter., 2015, 41,11960-11965.

11.Liying He,Lanhong Jiang, Shikao Shi*. Recentadvances of cerium oxide nanoparticles in synthesis,luminescence and biomedicalstudies: a review, J. Rare Earths, 2015, 33, 791-799.

12.Guangcai Zong,Jianxia Huo, Ning Ren,* Jianjun Zhang,* Xiaoxia Qi, Jie Gao, Lina Geng, ShupingWang, Shikao Shi， Preparation,characterization and properties of four new trivalent lanthanide complexesconstructed using 2-bromine-5-methoxybenzoicacid and 1,10-phenanthroline. DaltonTrans., 2015, 44, 14877-14886.

13.Xiaoxia Qi, NingRen, Suling Xu, Jianjun Zhang,* Guangcai Zong, Jie Gao, Lina Geng, Shuping Wang,Shikao Shi, Lanthanide complexeswith 3,4,5-triethoxybenzoicacid and 1,10-phenanthroline: synthesis, crystalstructures, thermal decomposition mechanism and phase transformation kinetics. RSCAdv., 2015, 5, 9261–9271.

14.Meiying Song, Longmei Wen, Shuping Wang*, ShutaoYang, Jianjun Zhang, Lina Geng, ShikaoShi. Syntheses, structures, magnetic andthermodynamics properties of tri-spin lanthanide complexes of nitronylnitroxide, Inorg. Chim. Acta, 2015, 430, 1-7.

15.Jinging Wu, Shikao Shi*, Xioalong Wang, Jibiao Li,Ruilong Zong, Wei Chen. Controlled synthesis and optimum luminescence of Sm³⁺-activated nano/submicroscale ceria particles by a facile approach, J.Mater. Chem. C, 2014, 2, 2786-2792.

16.Qing Liu,Haijiao Yan, Yumin Su, Shikao Shi*,Jianping Ye. Energy transfer studies of dye chromophores in modified zirconiumphosphate framework, J. Lumin., 2014, 251, 238-240.

17.Jingjing Wu, Shikao Shi*, Xiaolong Wang, HuihuaSong, Ming Luo, Wei. Chen. Self-rising synthesis and luminescent properties ofEu³⁺-doped nanoceria. J. Lumin., 2014, 152, 142-144.

18.Ruilong Zong*,Xiaolong Wang, Shikao Shi, YongfaZhu. Kinetically controlled seed-mediated growth of narrow dispersed silvernanoparticles up to 120 nm: secondary nucleation, size focusing, and Ostwaldripening.Phys. Chem. Chem. Phys. 2014, 16,4236-4241.

19.Xiaolong Wang,Ruilong Zong*, Shikao Shi*, YongfaZhu. Ultrasensitive and reproducible surface-enhanced Raman scatteringdetection via an optimized adsorption process and filter-based substrate. AnalyticalMethods, 2014, 6, 4130-4137.

20.Shikao Shi*, Qing Liu,Xing Zhang, Ryan Hall. Fabrication and spectroscopic properties of ametalloporphyrin-intercalated zirconium phosphate assembly, RSC Adv., 2013, 3, 8254-8260.

21.Shikao Shi*, Yan Zhang, QingLiu, Ji Zhou. Hydrothermal synthesis and characteristics ofanions-doped calcium molybdate red powder phosphors, Mater. Res. Bull., 2013,48, 3943-3947.

22.Dandan Zhang, Shikao Shi^*, Ming Luo, JiZhou. Solid state reaction preparation and enhanced red luminescence of S-dopedLa₂Mo₂O₉:Pr³⁺ phosphors, Ceram.Int., 2013, 39, 6299-6302.

23.Shikao Shi*, Marius Hossu, Ryan Hall, Wei Chen. Solutioncombustion synthesis, photoluminescence and X-ray luminescence of Eu-dopednanoceria CeO₂:Eu, J.Mater. Chem., 2012, 22, 23461-23467.

24.Shikao Shi*, Huili Gong, Jingjing Wu, Ming Luo, Ji Zhou. Synthesis of Eu³⁺-activated La₂Mo₂O₉ powder phosphors bysurfactant-assisted hydrothermal approach. J. Am. Ceram. Soc., 2012, 95, 3878-3882.

25.Xing Zhang, Shikao Shi*, Qing Liu, Ji Zhou,Jianping Ye, Cailan Yu. Tris-(8-hydroxy-quinoline)aluminum/ zirconium phosphate: a novel hybrid assembly with strong luminescenceand prolonged lifetime. Chem. Commun.2011, 47, 6359-6361.

26.Huili Gong, Shikao Shi*, JiZhou. Enhanced red luminescence of Eu³⁺ and R³⁺ -doped La₂Mo₂O₉phosphors under blue light excitation. Curr. Appl. Phys. 2011,11, 551-554.

27.Shikao Shi*, Ji Zhou, Shitian Han, Jianping Ye. Luminescence and energy transfer of organicchromophores bound to inorganic nano-lamellar frameworks. J. Nanosci.Nanotech. 2010, 10, 1834-1838.

28.Yan Zhang, ShikaoShi*, Jing Gao, Ji Zhou.Effectsof SO₄^2- or SiO₃^2- doping on the photoluminescenceof NaEu(MoO₄)₂ nanophosphors for light-emitting diodes.J. Nanosci. Nanotech. 2010, 10, 2156-2160.

29.CuishengXi, Shikao Shi*,Huili Gong, Ji Zhou.Preparation and luminescent properties of Na₅Eu(MoO₄)_4-x(PO₄)_xred phosphors for white light-emitting diodes application. Mater. Sci. Forum2010, 654-656, 2025-2028.

30.ShikaoShi*,Yanli Peng, Ji Zhou. Enhanced stable luminescence and photochemical properties of ruthenium complex /zirconium phosphate hybrid assemblies. J. Nanosci. Nanotech.2009, 9, 2746-2752.

31.Shikao Shi*, Jing Gao, JiZhou. Promising red phosphors (Ca, Eu, M)(WO₄)_1-z(MoO₄)_z(M=Mg, Zn) for solid-state lighting. J. Electrochem. Soc.2008,155, H525-H528.

32.Shikao Shi*, Ji Zhou,Shitian Han, Yanli Peng, Jianping Ye. Optical properties of porphyrin chromophoresassembled in nano-lamellar zirconium phosphate. J. Nanosci. Nanotech. 2008,8, 1359-1363.

33.Shikao Shi*, Jing Gao, JiZhou. Effects of charge compensation on the luminescence behavior of Eu³⁺activated CaWO₄ phosphor. Opt. Mater. 2008, 30,1616-1620.

34.Shikao Shi*, Xingren Liu,Jing Gao, Ji Zhou. Spectroscopic properties and intense red-light emission of(Ca, Eu, M)WO₄ (M = Mg, Zn, Li). Spectrochim. Acta Part A.2008, 69, 396-399.

35.Shikao Shi, Ji Zhou*,Ruilong Zong, Jianping Ye. Spectroscopic studies of Tris(2,2’-bipyridine) ruthenium(II) intercalatedto modified a-zirconium phosphate. J. Lumin. 2007, 122-123,218-220.

36.Shikao Shi*, Jing Gao, JiZhou. Enhanced red emission in lithium doped CaWO₄:Eu³⁺and CaMoO₄:Eu³⁺ phosphor. Mater. Sci. Forum 2007,561-565, 1081-1084.

37.Shikao Shi, Ruilong Zong,Ying Liu, Yuehui Wang, Ji Zhou*. Characteristics of surfactant-zirconium phosphate composites with expanded interlayer separation.  Key Eng. Mater.2007,336-338, 2589-2591.

38.彭艳丽，石士考*，叶建平. 三(2,2?-联吡啶)钌(II)在磷酸锆层状物中的组装及光物理性质. 化学学报，2008,66, 937-942.

39.张艳，宫慧丽，石士考*，周济，叶建平.亚微米级红色荧光粉NaEu(MoO₄)₂的水热合成及光谱特性. 无机化学学报， 2009,25, 563-566.

40.石士考*，刘颖，韩士田，周济. 四苯基卟啉在改性磷酸锆层间的插入及荧光增强. 无机化学学报， 2007,23, 703-707.

41.宫慧丽，石士考*，高元哲，王继业，宋会花，周济. Eu³⁺激活的La₂(Mo,S)₂O₉粉体的结构及光致发光. 硅酸盐学报，2010，38，2247-2251.

42.李敬磊，李科研，石士考*, 蒋兰宏，王淑萍，耿丽娜，周济. 纳米粉体CeO₂：Eu³⁺的溶胶-凝胶绿色合成及其发光性质. 发光学报，2016，37, 405-409.

43.燕海姣，石士考*, 蒋兰宏, 王淑萍, 周济，吡嗪-2-羧酸在γ-改性磷酸锆中的插层组装及发光性能研究, 发光学报, 2014,35(7), 807-812.

44.张丹丹，石士考*，罗鸣，刘行仁，周济，Pr³⁺激活的CaMoO₄红色荧光粉的发光性质, 发光学报，2012,33(8), 840-844.

45.刘庆，张星，石士考*，宋会花，韩占刚，周济. 金属卟啉配合物在无机层状框架中的插入组装及光学性能.发光学报，2011，32，617-621.

46.席翠省，高元哲，王萍，石士考*，王瑞芬，周济.  白光LED用红色荧光粉LiGd(MoO₄)₂:Eu³⁺的制备和发光特性. 发光学报，2010，31，311-315.

47.高静， 石士考*， 王继业， 宋会花. 新型发光材料Sr₂CeO₄的研究进展. 稀土， 2008, 29, 60-65.

48.韩建伟，黄淋毅，王昌铃，石士考，刘行仁*. 白光LED用几种Eu²⁺激活的红色荧光体的性能. 照明工程学报，2009，20，18-23.

49.李雅，张彦，韩士田*，石士考，钟少雄，张建川. 对羧基苯基膦酸的合成. 化学试剂，2009， 31，203-204.

50.王悦辉*，周济，石士考. KCl对含有纳米银的[Ru(bpy)₃]²⁺荧光性能影响. 光谱学与光谱分析，2007，27，1377-1380.

51.宋会花*，杨芳，王继业，石士考. 均苯三甲酸铽掺杂（钇、钆）配合物的合成及荧光性质.光谱学与光谱分析，2007，27，2093-2097.

52.李亚娟，梁青，宋会花*，贾密英，石士考，张建军. 基于3,4-吡啶二羧酸配体的钆（III）配合物的合成、晶体结构及热性质. 无机化学学报， 2009,25, 725-729.

注：欢迎对材料化学感兴趣的研究生及高年级本科生到实验室工作。